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Most LED's don't like being reversed biased by more than a few volts so you will need to add some diodes to protect your LED.
Try this one.
**broken link removed****broken link removed**
I found a similar thread https://www.electro-tech-online.com/threads/convert-220-ac-to-3-6-vdc-for-lighting-led.36652/ however they are using Capacitors as well which will make circuit bulkier.
Will this circuit work too ? **broken link removed**
The circuit is halfwave and you will get 25Hz flicker, which is noticeable. 100n caps will only deliver 10mA in full wave or 5mA in your situation, so a few 100n in parallel is required. They need to X2 caps or at least 400v.Use 4007 instead of 4148 and 380nf or near about
The 1k is useful, as it reduces the surge when you turn the circuit on. Without the 1k, you are trying to charge the capacitor almost instantaneously.That 1k is not really required.