What works is when you have a problem to report all the node voltages clearly with labels or Ref Des. Even if you pencil on a schematic is OK.
Your LED may also be burnt out.
This is an active current limiter cct. Ic~0.62/Re= ~ 10mA depending on temperature and Q2 Vbe & base current.
The setpoint is Ic= Vbe(Q2)/R1 but Q1 needs to have enough current gain to work. When Q1 Vce = 0.7V is in the saturation region with low Vcc, hFE drops to about 10% of the max linear hFE.
Check that Vbe~ 0.6 with Ib=400 uA thus record Q1 Vc,Ve and Vf of diode.