Regulations vary by country. We do not know in which country the TS is located. I have experience in the US and owned various General Aviation airplanes from 1971 through 1990. In the US, what's required by our FAA varies by the type of certification (e.g., GA, Experimental, on-demand charter (Section 135), air carrier, and military). Turbines and max gross weight are also factors. Avionics require additional certifications, as the FCC is also involved. As I recall, PB has extensive experience in avionics. I suspect such dimmable windows are considered part of the airframe, not avionics.
With privately-owned GA, non-turbine, and max gross weight less than 12,000# (including a twin engine), I did almost all of my own airframe and engine work supervised by an experienced mechanic with IA (inspector authorization). A friend rebuilt a crashed Mooney and got it signed off. It's the TS's responsibility to be sure whatever is done is properly supervised and signed off. Modifications can be authorized by getting an STC (supplemental type certificate). STC's are not rare. All but one of my airplanes had at least one STC.
Dimmable windows are relatively new and intriguing. I hope the TS visits again and gives updates.