Go back and look at the picture you attached to post #4. It shows where to connect the panel, the battery, and the "load"
The panel you have will not work with this controller; you need one that outputs ~20V in bright sun!
The only battery you can connect to your controller is a 12V SLA; not a LiPo!
The "load" connection is for what ever you want to power with 12Vdc, in your case this is where you would connect a LiPo charger (not the LiPo battery).
Now read the following which comes right from the maker of your controller:
Product Description
Color:5A 12V/24V
Function:
. Always keep the battery on fill voltage condition.
. Prevent the battery from over-charging.
. Prevent the battery from over-discharging.
. Prevent the battery from reverse charging to solar panels during nights.
. Reverse Polarity Protection for Battery
. Reverse Polarity Protection for Solar Panels
. When the battery voltage is low, the controller will automatically cut off the load from the system. If the voltage of battery is back to normal and the load will restart working.
. Thunder protection
. According to the battery voltage grade, the controller can automatically set charge-off voltage, the load-off voltage, the load- restore voltage. (The parameter is default under 25¡æ condition, locked by the CPU procedure, cannot adjust.)
. The controller will automatically compensate the temperature of the charging voltage according to the changes of ambient temperature.
Warning:
Before connecting to the solar panel, please connect the controller to the battery; do not use solar panel supply power to the loads directly.
Notes:
Do not use lamplight to charge the solar panel (lamplight is too weak to charge)
DC power source to replace the solar panel will cause troubles to controller.
Choose the suitable wire which diameter should not be too small, please refer to the parameter.
Note the two Functions in the list above that I underlined.