Please please please please please don't think of using Windows Paint to edit images! Really.
This is a brain-damaged tool that just happens to come with every copy of Windows sold on earth. Just because it's there doesn't make it a suitable tool.
The only reason I can see to use it would be if there's nothing else available. At this late stage of the game (we're well into the 21st century), there are so many other good tools available, some for free, that it's a joke to suggest using Paint.
Myself, I've been using Paint Shop Pro for, well, decades now. It has a little less power than Photoshop, with a lot less bloat (program size), is fast, easy to use, intuitive, etc., etc.
If you're a fan of free, open-source software, there's always Gimp. Haven't ever seen or used it, so can't comment.
Then there are vector-based drawing tools (like Corel Draw, which I use, or Adobe Illustrator or InDesign, or many others) that may be more suitable to tasks like this; instead of messing around with pixels, you can easily draw the shapes that make up a circuit (lines, rectangles, circles and ellipses, arrowheads, etc.). For instance, this was made with Corel Draw:
**broken link removed**
Then there are the tools specifically made for drawing schematics: ExpressSCH is one, and LTspice comes with a rudimentary but adequate schematic editor.
Friends don't let friends use MS Paint!