You can bet that there will be regulations that cover what you want to do - although in my experience regulations are always pretty opaque. As other have said, it depends rather on where in the world you are.
In the UK and Europe, I think what you want to do may be covered by SELV (seperated extra low voltage) or PELV (protective extra low voltage), which would limit the voltage to 50VAC or 120VDC. Again, as others have said, it will depend somewhat on the environment and the people - if they are not the general public, you may get away with more.
My suggestion, though, would be to read up on SELV and PELV, and equip yourself with a regulations book if you possibly can.