If you leave the 12V input disconnected but with everything else connected - and no sun - what voltage do you get at the Ecoflow input?
Without actual loads connected, a digital multimeter may be reading from minuscule leakage currents that would have no effect with all parts connected.
If you get little or no voltage at the Ecoflow input, then try connecting something as a load at the 12V connector - a resistor, 10K or so, or a a low power filament lamp, and see what voltage you get across it with the solar panels producing a good output?