From the data sheet, this may do the trick:
"The I2C interface is accessible whenever either VCC or VBAT is at a valid level. If a microcontroller connected to the DS3231 resets because of a loss of VCC or other event, it is possible that the microcontroller and DS3231 I2C communications could become unsynchronized, e.g., the microcontroller resets while reading data from the DS3231. When the microcontroller resets, the DS3231 I2C interface may be placed into a known state by toggling SCL until SDA is observed to be at a high level. At that point the microcontroller should pull SDA low while SCL is high, generating a START condition."