Low side or High side is based on the output devices switching to ground or switching to power, rather than the transistor configuration - eg. a PNP or P channel device with emitter or source to V+ is a high side switch.
In anything to do with industrial control, safety related or where a false signal could cause harm or damage, high side is required - main on the basis that a fault to ground will prevent a thing operating or blow a fuse, rather than doing the same as a low side switch and activating something.
But, an NPN low side switch is the simplest to control a 5V or higher load from a 3.3V MCU or logic IC; (or a 12V load from 5V etc).
I'm not fully grasping what's needed in the schematic (ie., I don't understand the purpose of R2 above, nor how/why to add the diodes, let alone how to properly select the right component).
With that circuit, R13 is not needed, its just in parallel with R1 - but you do not have a series base resistor, so there is a direct path from 5V through the phototransistor and base that can take excess current.
This is what I was trying to describe, tidied up a bit:
(R3 and R4 should actually be a lot higher; 10K or more, I was just copying and pasting & missed changing the values. Also ignore the opto part types, they are just to represent what you are using)
With the MCU pin as an input, it just senses the circuit state.
Set it high and briefly set it to output, and it should switch the circuit on via D2.
Set it low and briefly set it as an output, and it should switch the circuit off, by D3 bypassing the drive to Q2 base.
(D1 means there must be more like 1V at the right of R2 for the transistor to be on; that means the MCU pin when LOW can pull that point down far enough via D3 to remove the base current).
It does need testing in practice - eg. Can the MCU 3,3V output provide enough current after the voltage drops from D2, D1 and the base-emitter voltage drops, to reliably switch it on??
R2 could be split to two lower value resistors totalling around 2K, with D2 connected to the mid point, if needed.. Only the right half would be in the switch-on path.