Well there's the obvious synchronous rectification, using controlled FETs as diodes, to reduce the diode losses.
What I will say is that inductors are everything. Besides being hand wound, we had to get the main inductor core material made overseas to my specification of minerals using some exotic minerals (basically aerospace quality inductor core material) to get the switching freq low enough and maintain the required magnetic properties. That might give you some idea! I'm not an expert on the magnetic minerals, and I don't think I've used magnetic formulae since 1983 in DC-machines class, I just did a lot of trial and error testing on the CRO with sample cores and refined it down to the right properties to suit our needs, then had a production batch of cores produced to that spec.
90% is pretty easy. 95% gets harder, 95% with good reliability, high current density, smallish size, large operating range and decent cost effectiveness gets real hard.
As for a multiphase system I have never done one, give me a nice simple buck regulator or push-pull voltage transformer anyday.