Each LED, or series string, will need it's own current limiting resistor. What LED are you using? What is its rated operating current and forward voltage? You need to know those numbers to calculate the resistor value.
But I will ask one other question. What is the power source for your system? Is it 5V only, or is there a higher voltage available? If so, running the LEDs in series or series/parallel is generally a better choice. For instance, if the LEDs have a fv of 2V at 100mA, you can put two of them is series with a 5V source, and, since the same current runs through two parts, the efficiency is more than double that of running a single LED But, if you have 12 volts, you can put 5 or 6 in series using the same current. Even though you do need the higher voltage, you will probably waste less power in the limiting resistor.