Taking the signal from a thermocouple and turning it into a temperature reading is not terribly difficult, but getting decent accuracy is complex. Specialty chips make a huge difference. But . . .
If all you want to do is determine if things are above or below a setpoint, then you can do this with a comparator, plus maybe a preamp before it. The LM358 is not anything near a precision opamp, but it should be good enough to produce a go / no-go signal. (See what I did there - I read the title.)
Is this school work, a job assignment, or - ?
ak