It's tempting to think you could use the Powershot's built-in flash to fire slave strobes — this is a very appealing idea and in fact it works very well with many other cameras that have built-in strobes. It's not dependable with the Powershot, however.
The Powershot's built-in flash uses Canon's E-TTL metering system. E-TTL fires twice for a single exposure — once at low power to meter the scene, and then once at full power (or whatever) to expose the image. Upside: very good range of exposures. Downsides: (1) a delay between the time you press the shutter and the exposure, and (2) the first flash will set off your slave units, which will fire and overexpose the meter reading but be unable to recycle quickly enough to make the second, real, exposure.
The safest way to use optically-slaved strobes with the G1 is to trigger them from another external unit. I typically use my old Canon 199A (a speedlite made in the era of the A-1) for this task — it can be swiveled off to bounce from the ceiling while the slave units do the bulk of the work (recently, to avoid any chance of being bitten by the wide-angle mistiming bug, I've been using the 550EX instead. Pretty pricey for a slave trigger!).