What I do with unknown inputs/outputs is use a standard 24V AC transformer as a feed, then measure the voltages on the other side. Then reverse... That way, you know by a factor of 10, what the voltages will be with 240V (or 220V pro-rated). You can use just about any transformer, 12V, 18V, etc. and thus relatively safely measure the voltages at the other end.
If the transformer is from a UPS, odds are high that the switched battery input would be the heavier wires, and the smaller wires would be the output.