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According to the data sheet fragment, it looks like it will work as long as both inputs are constrained to be between Vss and Vref.
Why are you opposed to a differential input? This will keep your system more noise free. Otherwise, why not use a simpler ADC?
Mike, we already source from Microchip ,therefore its easy to choose their products. In my application I am getting conditioned 0~5V single ended signal and need to know if this is doable with the above ADC .