.. if these supplies are in chassis boxes, and have a ground pin on their AC line cords, you want to make sure the chassis box is isolated from the 12V supply or you could end up with a short across the "b" supply when the supplies are plugged into the wall outlet.
another method would be to run a DC-DC converter that outputs -12V@10A when driven from the +12V rail. since the DC-DC converter is running off the same supply used for the +12V supply, you will be drawing about 22A from the power supply when each rail is loaded to 10A.