First of all, lets clarify. "Line of sight" simply means you have a direct "free space" path between transmitter and receiver antenna. However, if your receivers are moving that may not always be the case.
Now its true there are different kinds of modulation schemes that work better depending your line of sight (and more importantly your SNR). So if you know for a fact that you'll have line of sight at all times, look for a transmitter/receiver pair that does some type of digital modulation. Frankly, analog modulation (AM, FM, PM) schemes suck, they have terrible bandwidth requirements and transmitter draw backs. But they are easy to do, which is the appeal. Especially AM, it is super easy to demodulate since it is a coherent modulation scheme (no synchronization required), but thats not the case for FM and PM. Now if you actually look at FM, you'll notice one interesting characteristic about it, it requires infinite bandwidth, (which is the reason for the 200Khz guard bands on your FM radio). But there is a rule (called Carson's Rule) given a few variables you can calculate your 99% bandwidth requirement.
The main draw back of digital modulation schemes is the obvious need for a ADC and DAC, but their SNR requirements, BER, and Bandwidth efficiencies more than make up for a few extra parts.
I recommened either a M-ary PSK modulation, a QAM modulation, or an FSK modulation, either will suit an line of sight application well. You will also be able to get much higher data rates with a digital scheme. For the most part the only type of modulation that is really still done in analog land is the radio. Surely you have an RF front end, but thats only for the up conversion, that doesn't do the modulation.
Good luck!