As I have explained the circuit I posted is a 'behavioural' circuit NOT a LM331, so it will not have the pins shown for the LM331.
I have tried in a number of ways to help you solve this problem , but I cannot offer any further suggestions.
Look again at the 'behavioural' circuit that represents a LM331, you may realise that to complete your full circuit design simulation, that circuit will do the Voltage input to Frequency out operation of a LM331.
lm311.301 is the spice model. You'll see that if you view it with a text editor.
Forget about the .olb files...they won't work with LTSpice.
The .lib files are also spice files but contain multiple models.
You can use the .lib and lm311.301 with LTSpice...but you have to take the time to learn how to add
a new model and symbol to LTSpice.
Google "LTspice model tutorial"... you should get some hits...