You mean a bandgap energy smaller than that of metal, not conduction band itself. The amount of energy required for an electron to jump from valence to conduction band decides whether it's insulative, conductive, or semiconductive, not the "size" of the conduction band itself. In conductors the valence and conduction bands overlap (negative bandgap energy if you will)- the more they overlap the more conductive it is.
There's a lot of space between the atoms of a gas though so even if the material's bandgap makes it conductive, the resistance would still be high.