I just use bits of black insulating tape for reading items with an IR thermometer.
If you need to see individual small components, a consistent colour may help. Be wary of matt black paints, some contain carbon / graphite and are conductive.
You could use a black "permanent marker" - that has the advantage it will wash off many things with IPA, if you do not want a permanently black PCB.
The most important thing is to have an uniform emissivity across all the different surfaces and materials, which on a fully populated board, will be all over the place.
Matte black has the additional advantage of an emissivity approaching 99%.