most sources list the breakdown voltage of air as 3kv/mm, so at 800V and 2.5mm spacing you have a long way to go. what you might want to do however is to not use PCB pads with points (use round pads, not square) and use high voltage soldering technique (a little bit of extra solder to give the connection a spherical profile, no points, no inclusions and no bubbles in the solder). clean all flux residue off the PCB. at 800V, PCB traces might have some corona discharge around the edges, so painting them with HV dope will keep that from being a problem. the other thing that HV traces on a PCB do that can eventually cause arcing over, is they gather dust. again HV dope painted over the traces will help keep the trace isolated from the dust that collects (it will collect because there's an electrostatic field).