A fixed PWM period will do a poor job of tracking the mpp of the solar cell. It'll work so-so, your system is low on power already so it may be close to nonfunctional if you lower performance any more.
Will the following incease the efficiency of the DC/DC converter?
I have a PWM signal that varies according to the voltage output at the solar panel instead of according to the 12V battery.
Meaning, example:
If the output voltage of the solar panel is 7.5V, I will step-up to 13.5V.
If the output voltage of the solar panel is 8.5V, I will step-up to 13.5V.