I got interested in the using LEDs as photo-detectors. I tried some moderately bright red LEDs that I have laying around,
similar to these. They are in a water-clear T1 3/4 lens. I do not know their viewing angle; i'm guessing they are the 30 degree variety, because they were bought for indicators.
Shunting an unbiased LED with a 1megΩ resistor, under outdoor illumination on a very cloudy day, I get about +350mV anode to cathode, using a Fluke 73 DMM (>10meg input impedance). The LED is directive, consistent with the "viewing angle" shown on the referenced data sheet.
I then connected two LEDs in parallel, which approximately doubled the output voltage, indicating that the current produced by the LED (into the 1megΩ resistor) also doubled. I then reversed one of the LEDs so that the pair is connected in inverse parallel with the 1megΩ resistor, and bent their leads so that their optical axes diverged by about 45 degrees.
The 2 LED array produces +- 200mV as the array is panned across the sun, with
zero volts out when the optical axes of the two LEDs roughly bisects the angle formed by the two axes. Seems like this could be used to drive a
solar seeker, because the 2 lLED array puts out a signal which goes from +200mV to zero to -200mV as the sun angle changes.
PS: The sky just cleared, and I took the array outside again. Here at 42degrees North Latitude, I was able to get the output to go from -1.4V to +1.4V by pointing first one LED and then the other at the sun.