Minor typo in my post above: I meant to say that aluminum OXIDE is very resistant to flux...
Nigel, have you ever had any luck actually getting a bond with aluminum solder and flux? Is is possible that none of this stuff actually works and there is a whole industry feeding off our wishful thinking that it is possible, like free energy?
Well, one of the books out of my library that has not composted yet is, "Soldering Alcoa Aluminum," by, coincidentally, Alcoa. They make it seem like a slam dunk, but with a few cautionary notes. They recommend 95Zn-5Al solder or pure zinc solder and Alcoa flux #66A, which they describe as a high zinc-chloride flux. They emphasize the importance of not overheating the flux, either with a flame or an iron, both of which they say can be used. Overheating the flux produces reaction products that block solder bonding. If a flame is used, it must be a reducing flame, i.e., a slight excess of fuel relative to oxygen. This is easy to obtain with an oxy-fuel torch, but I don't know how you would obtain it with a standard propane torch without separate oxygen control. Maybe by blocking off some of the air intake ports.
They say conventional soldering irons and guns can be used with low-temperature solder #408 and Alcoa #64 flux, with the precaution that the iron should be kept out of contact with the flux to avoid charring the flux. The iron can be tinned with tin-lead solder, so I guess there is no problem with "lead poisoning" of aluminum solder.
Hi eblc1388: Method #10 in their "Methods.." chapter is "Rub soldering or solder coating." They say the solder "easily" (Hah!) wets the fresh metal surface that has been rubbed with a solder stick or iron or wire brush or glass fiber brush or scraper. This is using heat from a torch, iron, or hot plate, not froction alone. I think you might have difficulty doing it without some external heat. (On the other hand, I think you will have difficulty doing it with ANY technique or materials. Do I sound bitter?)
Good luck.
awright