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Why would you want to go to all the effort of trying to write directly to the hard drive when it's so easy to turn on the pc?![]()
The PC would need to be on to provide power to the hard drive and USB ports.
It is possible with buffers / digital switches and some serious microcontroller programming.
What is your level of electronics and programming ? Do you have any microcontroller knowledge ? Have you looked at the USB protocol and also what is needed to communicate with a SATA device ?
You would be better looking at putting a small Linux system on the USB stick and a routine/script to copy what is in a certain directory or partition on that stick to the PC internal hard drive in a certain directory then perform a machine power off. You'd then set your boot sequence on the PC to boot from the USB device first.