T = R x C
That's the equation - you can't alter it.
As I always say, their name is stupid (giving people a wildly exaggerated idea of what they are) - such as why you're even asking this question?
There are applications for them, but reliability has always been a big issue as well, with massive failure rates when they were used as memory backup in VCR's etc.
You can't alter the discharge formula, best you can do is a switch-mode up/down converter on the output to maintain a stable output voltage over a vastly improved range - but it's only enabling you to get more useful energy out of the capacitor, not increasing the amount stored.
For portable energy storage batteries are
VASTLY superior.
Anything called 'super' or 'smart' (like smart TV's) is generally nothing of the kind, hence the name to try and con the gullible into believing it's something it isn't.