I don't think that the ripple is a problem in itself. I think that the problem is that the DCDC charger is expecting to be able to draw lots of current from the 12 V supply. In effect, it is expecting a battery or a much more powerful supply.
Have you tried connecting the alternator output to the solar input on the DCDC charger? The voltage / current curve of a solar panel will be similar to that of the alternator so the DCDC charger may work out that it can only use the 8A from the alternator. Are there settings on the DCDC converter that can change how fast it tries to charge the Li battery?
Just as background information, a solar panel will produce a certain amount of current, and altering the load voltage won't change the current much until the maximum voltage is reached. An alternator is similar, in that the current it produces won't change much if the load changes, until the regulator limits the voltage.
Batteries are completely different, and the current they produce varies a lot as the load changes.