you might want to put a variable cap across that loopstick so you can tune it. for 100khz, you might want to use 2 sections of an AM tuning cap to get about 600pf.
If I tune the loopstick to 3rd harmonic below 100kc I get some signal, and if I tune to 66.6kc I get a good signal, not sure whats happening there.
a) what are you using for a radio? b) "3rd harmonic", and "below" are mutually exclusive, as a harmonic of 100khz will be a multiple of 100khz, i.e. 200khz, 300khz, etc... every once in a while there are textbooks that mention "subharmonics", but there don't seem to be any distortion mechanisms in practice that actually generate them, except a PLL seriously out of alignment. c) what you are seeing is likely to be an image in the SDR. it would help to know the sample rate and center frequency when you see the image at 66.6khz. theres a phenomenon with SDR radios known as "wrap around", where signals from outside of the passband show up. sometimes they are caused by strong signals generating IMD, or they have some mathematical relation to the sample rate, and center frequency. if you do effective filtering of the AM broadcast band, i think most of the images you are seeing will go away. also, SDR radios with 8-bit ADCs have a limited dynamic range, and the real cheap ones don't have baseband filters, so images and wraparound effects are more common with them. i have a regular RTL-SDR, a HackRF, and an SDRPlay radio. the RTL-SDR and the HackRF have 8 bit ADCs, and the RTL-SDR definitely has images and wraparound. The HackRF has baseband filters, and it's performance is better, but i can definitely tell that it has problems with images under certain conditions. the SDRPlay has 14 bit ADCs, baseband, and broadcast band filters, and i don't think i have seen any problems with images, except when the gain is cranked up too high. under normal usage it performs pretty well. what you should try is when you think you might be seeing an image, step the center frequency up 10 khz at a time. images will move the opposite direction in the waterfall from other signals. wraparound is more difficult to detect, but if you know what frequency a signal should be on, and you see it somewhere else, it's wraparound.