Sorry about the lack of updates. I'm having some major home PC hardware problems that are still unresolved.
Anyway, I decided to start with the 12D4 Radio Corporation of America (RCA) diode, since it was the simplest on the list.
Filament Test:
Testing the filament was the first step. These tubes seemed to be fairly old, and I'm guessing printed date codes weren't common back then. I honestly didn't know what to expect if the filament had failed. To start, I checked the resistance across the two filament pins indicated by the datasheet (pins 7 and 8). The resistance matched what the datasheet implied. (The filament resistance isn't explicitly called out, but dividing the operating voltage of 12.6 V by the 0.6 A filament current yields the nominal value). The resistance was high enough to seem safe, so I connected the filament pins directly to the 12 V SLA battery...first for a split second, then for several seconds.
Luckily, there were no sparks, explosions, or wormholes created. The filament glows a nice orange, and you can see this along with the filament current in the attached image.
Diode Forward/Reverse Current Test:
I did a second resistance test to check for any conduction between the cathode and anode (plate). There was none, so it was looking safe to proceed testing the diode/rectifier function. I used a second SLA battery to supply the anode and cathode. I could have run the whole thing off one battery, but I wanted to see the filament run independently for now.
The datasheet indicated an anode voltage of +12 V should result in about 100 mA forward current. Sure enough, when I applied the 12 volts, the smaller current meter reported just over 100 mA. Reversing the voltage or applying voltage after cool-down resulted in no measurable current. So I think this one has PASSED.
Overall Impression:
So far it's going pretty well. I've read a little about tubes in the past, but they really only get a passing mention in most organized courses. I really wasn't sure of what to expect. It's also worth noting I did not restore the tube in any way prior to testing. That is: I didn't clean the pins or remove any dust or debris before-hand. I might clean them on a later date. The pins, batteries and meters were all connected through alligator clip wires.
I found the data for this tube on the site:
http://www.nj7p.org/Tubes/PDFs/Frank/093-GE/6DA4.pdf
Unknown Data:
As far as rare/unusual materials go, I'm not sure if this tube contains any. The General Electric (GE) datasheet indicates the envelope is "T-9" glass. I'm sure of what that is (maybe borosilicate or phosphosilicate glass?). Also I've heard the color of the filament can provide clues about its composition (white for tungsten, bright yellow for tungsten-thorium alloy). This was clearly orange, so maybe this is a different material entirely.