Most ADCs built in to ucontrollers are ratiometric to a voltage reference, which is typically the VDD for the chip (0 to 5V); sometimes to a built-in 2.5V voltage reference (0 to 2.5V).
You should amplify your signal so that it almost fills the full dynamic range of your ADC, whatever it says on the chip's data sheet.
What is the form of this voltage from the audio detection circuit, AC or DC? The ATMEGA32 has an A/D converter but it can only handle positive signals from 0V to Vcc, so if the signal is AC you will have to generate a DC offset to convert the signal. Two of the differential inputs have a selectable gain of 10X and 200X.
The ADC gives a binary number between 0 and full scale.
You can write it as a hexadecimal or decimal number if it is convenient for you but the ADC still only gave you a binary number.
Example: If an 8-bit ADC full scale is 2.55 volts and its input is 2.55 volts, it will give you a result of 11111111. If your input is 0.7 volts the result is 01000110. If you need a human readable "0.70" your software must do it.