Well, bottom line is this- a charge pump is not possible to use here. It'll take too long to explain why if you don't know. It's not gonna work on any practical level.
Pulsing an inductor as a "boost" converter to make non-isolated 100v from 12v is only good for very low power levels. The high vout/vin ratio boost converters don't work really well with significant current, the transistor, inductor, and capacitor sizes become impractically huge.
A 20 amp/100v output requires exceptional performance. What standard car power inverters do is use transformers. Usually with a center winding at 12v and two poles alternately pulled down with NMOS. It's possible to use an h-bridge but this one seems to be preferred, since it saves on expensive/complicated high power/high freq transistor stages.
The output is FWB rectified to a DC rail somewhat over 120v (there is a dead time between positive and negative phases, and RMS needs to stay at 120v).
In fact, lemme just say it. Building a 20A output inverter is WAY beyond your apparent skill level. There's like a dozen very "hard parts" here.
Best idea is to get a power inverter off the shelf, FWB the output to make the high voltage DC rail again, and build a stepdown converter. Although, gotta tell you, a 20A high voltage stepdown converter is already beyond your skill level too (and this will cost a LOT in parts and development).
Might be better to feed the power inverter output into a big-ass variac, put it on a FWB rectifier and filter, and adjust the variac to get 100v. That's the cheapest and most likely to be successful option. It'll still cost you a bundle, a 2KW continuous inverter is not cheap, nor is a 2KVA variac, nor HV filter caps with 20A of ripple rating.
All this is beside the point if you don't have a DC source capable of ~200A. A car battery will only supply that for a short time. Even a running car would need a HUGE alternator to sustain such high current.
WTF do you actually need this for? 20A of 100V DC??