I think it can. Because even if e^x can never reach 0 becoming smaller and smaller, charge of real capacitor consists of electrons and you can't have charge less than one electron's charge. So when the "last" electron will go to cap, if next electron will try to move to cap, voltage on cap will be bigger than supply voltage, so it won't do that, cause electric field of other electrons in cap won't allow him, so we can say, that cap is fully charged. But in real life we haven't power supplies with one electron charge voltage precision, so there is always small current trough capacitor caused by power supply fluctuations.