Isolation Check
(1) Disconnect everything you can from the "isolated" supply
(2) Put a multimeter to the ohms/continuity setting.
(3) Hold the probes together, note what the meter does.
(4) Hold the black probe to the ground of the "isolated" supply.
(5) Scratch the red probe tip into the metal case a bit. (To get good contact to fresh metal below it.)
*IF* the meter reads the same as when the probes are connected to each other, then the PCB is not properly isolated from the case. Otherwise, you should be good.
Here are some things to check if test shows problems. These things are a mix of long shots you would never think of and common sense stuff that's easy to overlook. But the basic idea is simple, we are looking for ANY connection that exists from the main PCB ground to the case still.
(1) Did you put washers on BOTH sides of the PCB?
(2) Is the screw holding down the PCB making contact with any traces/copper on the PCB? (The inside of the PCB hole sometimes has metal.)
(3) Is the divider under the PCB missing any pieces or misaligned?
(4) Are there any protrusions from the case that could be touching the PCB?
(5) Is the green ground wire from the mains power socket screwed to the case, or the PCB? Is the screw screwed into the case?
(6) Is the new fan circuit wiring to anything other than it's own power? If so, is it case ground?