Hi,
Well your first lesson is that Microchip datasheets are a terrible place for the beginner as they do not give the info in an easy to understand way.
What you are looking for is first the I/O Port A section which give an example of how to initialise the ports.
Your point about finding out what the Power On Defaults, its the Resisters like PORTA, TRISA ,ANSEL that set the defaults - you can see them in Table2 page 32 of the datasheet
If you are using the 16F690 and Pk2 do you have the Low Pin Count tutorial that usually comes with the MicroChip starter kit ? - it has lessons with complete projects to help you get going - have attached the pdf here, you can download all the project code from the Microchip site.