The daytime running function on main beam puts both headlights in series, therefore running them on about 7 V each, with one reversed. That relies on the headlight bulbs:-
1) being about quarter brightness on 7 V
2) sharing the voltage equally
3) working the same with reversed polarity
White LEDs are 3 V each, and so LED bulbs are made of several LEDs and some driver circuit. Without knowing a lot more about the driver circuit, the LED bulbs could fail any or all of the three conditions. I've never seen a circuit that would meet all of those three conditions. It would be possible to design one that did, but it would cost more and the LED bulb manufacturer would have little reason so do that. Your LED bulbs may not be suitable for dimming at all.