The circuit only implements a single switching cycle. At the least, you'll need to specify a period for the pulse generators if you want them to run continuously.
You're going to either need to implement some sort of controller or at least start start by calculating the average inductor current and duty cycles necessary for a presumed steady state load. As it is, the V1 on time is too long; watch inductor current in the first cycle. The converter is also operating in discontinuous mode despite a significant load, so the output voltage swing is huge. I'd say start design calculations as if this were a 36v buck converter, and then work in how much of the on-time can be shared by the 12v source.