It is a good idea to take the manufacturer's word as gospel, otherwise, you have nobody to blame if things go poorly,
The datasheet, in section 20.7, says:
Since the analog input pins share their
connection with a digital input, they
have reverse
biased ESD protection diodes to VDD and VSS. The
analog input, therefore, must be between VSS and VDD.
If the input voltage deviates from this range by more
than 0.6V in either direction, one of the diodes is
forward biased and a latch-up may occur.
In other words, echoing what
rjenkinsgb wrote in post #8:
Good design means always keep voltages within the correct limits. Use an external means of limiting input voltage on this chip.
rjenkinsgb also wrote:
That's an example of why you should never rely on the input diodes as part of the overall circuit function.
So forget the maximum I/O current and just keep the voltage within limits as discussed above.
There are microcontrollers out there that specify the maximum current that can be injected into the protection diodes without causing SCR latchup, but this is not one of them.