I don't want to understate the real dangers of capacitors in high voltage systems, but you seem to be way over-thinking this.
In this case, I suggest that you approach the problem like this:
1 Switch off and disconnect from the mains supply.
2 Use your multimeter to measure the voltage on the capacitors.
3 If there is a significant voltage (greater than 1 volt) on the capacitors, discharge them.
4 You can use a screwdriver to discharge the capacitors. This can crack and spit and spark a bit and make a mess of your best screwdriver.
5 Or you can use a low value resistor, say 100 Ohm to 1 K Ohm to do the discharging, much less dramatic than the screwdriver.
6 Don't be surprised that once discharged, the capacitors magically charge themselves back up to a few volts. This is just the capacitor dielectric releasing internally stored energy.
7 Discharge again of you are worried about point 6.
8 Have a look at the capacitors, some designers will put a resistor across the capacitor to ensure that it discharges anyway, often the circuit which is being powered by the capacitors will discharge them to a safe level as power source is switched off.
JimB