Something is way off.
I simulated your power stage and I get a resonance at 1.5khz.
One thing I tried, I placed a 470u cap with 2 ohms in series across C24, it flattens out the peak nicely.
If you are not mass producing these that would be a good idea.
Being voltage mode I'd start cheating a little and use this calc:
https://www.exar.com/appnote/anp-16_typeiiicalculator_101206.xls
It is meant for sepic converter Ic's with a 1 or 1.1v ramp, not sure what the sg3525 uses, but for the Tl494 which is about 1.5v it gives ball park figures.
Have you tried simulating the entire circuit?
I've not done much with active clamp, does the '3525's 'b o/p switch fast enough to catch the spike?