LtSpice showed only what you asked of it, but you didn't do the required steps to see if the regulator covers the range of inputs and expected outputs..., or if you are stressing any of the components...
First, here is how to use LtSpice to test the Output Voltage Regulation as a function of Input voltage, V1. The regulator has a 5mA load. The input voltage ranges from 1V to 36V (see X axis). You can see what the minimum input voltage for regulation, about 6V...
I plot both the Zener voltage V(z) and the output voltage V(out). Note that the regulator's V(out) changes 163mV as V1 changes from 6V to 36V, or 0.5%. I also plot the power dissipation in the Zener (<20mW, ok) and in Q1 (160mW which is getting up there).
Second, here is how to use LtSpice to test the Output Voltage Regulation as a function of Load current. The input voltage is 36V; you might want to repeat this test at V1=minimum.
I vary the output load from 1uA to 10mA. The log of load current is the X-axis.
I plot both the Zener voltage V(z) and the output voltage V(out). Note that the regulator's V(out) changes -240mV as Load current changes from 1uA to 10mA. I also plot the power dissipation in the Zener (<20mW, ok) and in Q1 (310mW which is quite high for that transistor).