Hi there,
First off, you dont get a forward voltage based on Rs alone. The diode part (N and Is) contribute to the voltage drop too, and quite a bit.
Where did you get the Is, Rs and N parameters from, and where did you find the data sheet?
It is usually possible to emulate an LED using the spice "D" general model. If you got those three parameters from a reputable source then maybe something else is wrong, or else those parameters need adjustment for your exact LED.
BTW, how far off is it?