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All kinds of neat things on that site duffy! Good find.
Any power created by a peltier device in operation is automatically electrically regenerated into the circuit itself. So it's either increasing it's cooling effect through thermocouple effect or re-supplying the bus itself with power from it. If you do NOTHING at all you automatically recover the maximum amount of thermoelectric power without doing a single thing.
If you want power from your PC, you'd have to recover the heat from the CASE itself.
it would be a bit of educational fun more than anything else
Do some web search for a Seebeck junction. its the more efficient power producer, less efficient heat pump device. him an peltier did independent reasearch I think. one was doing power from temperature differentials the other was doing heat pumping from voltage differentials. Very similar but not the exact matrials used in both, I think.
The thermal difference needed for those isn't too bad. They claim 260mws for a 1.6X3.2 mm square TEG, but they're ungodly expensive. The evaluation kit is almost 300 dollars for a thumbnail sized device.