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With 4 AWG, I assume you are talking abut "welding cable" or at least something that is flexible. I would not recommend soldering 4 AWG; although, that size is a bit borderline. Generally, for 6 AWG and above, I just use crimping. The heaviest wire I have dealt with more than once is 00 (20).
A suitable crimper at McMaster-Carr is now $33.00, which means you should be able to get it for abut $25 elsewhere.
https://images1.mcmaster.com/Contents/gfx/large/7061k12p1l.png?ver=281326
John