ok, going back to my original question it seems that Spec - you are talking about clamping / over voltage, I am not doing anything for that (its built into the motor shield already).
I want a way to get the regen energy off the motor shield. I dont want to generate this energy either, it's an unwanted bi-product that can cause a problem, so I am seeking a way to get rid of it. So MaxHeadRoom78 - I dont want an alternator with a wound field and regulator etc.
All I really wanted is the spec of a diode that would allow energy created when the electric motors of my robot are spinning and the circuit is open i.e. turned OFF.
As a result of the motors spinning there will be energy created, this has to go somewhere i.e. back to the battery, I wanted a way to allow this even when the circuit has been cut because the circuit is turned off.
The way to do this was a simple diode in parallel with the switch, not from the output of the switch to +ve. So for anyone reading this in the future - the correct circuit is the one at the top, i.e. a diode placed across the pins of the switch, thus allowing run-off in a single direction back to the battery.
The rating of the diode should be roughly the max current the robot could generate running downhill with everything turned off and the motors in free spin with no breaking (assume everything has failed i.e. all fuses are blown, shield is off etc.). In my case this is about 20A, the whole thing is running <12 volt, so a diode rating of below 12v and can handle 20 A or below should be good.
Thanks everyone. Here is the latest correspondence from the motor shield manufacturer in response to having the diode placed from switch out to -ve.
QUOTE FROM ROBOCLAW BELOW
"That would be a diode used to clamp an over voltage(If I understand your description). You would usually use a TVS diode for that(and we have them on some models of the Roboclaw just for that purpose).
What we want is a simple one way path back to the battery if the switch is turned off or the fuse blows while the motors are spinning and energy is moving into the battery positive terminal we dont want to prevent that(bad things happen if the regen energy cant go anywhere)."