Heat and Molecular Speed
So, it would be fairly safe to generalize that when someone says that the molecules "collide" it's conceptually accurate? Much like thinking of pool balls knocking into each other when in fact they never do touch.
I have a problem with the "restoring force" thing as a way to explain the speed of sound. I can't make it jibe with the speed of sound remaining constant when there's a change in pressure (and, thus the molecules are physically closer or further apart).
I read an article that said that the attractive force is so weak, at the molecular level, that it can be ignored in most cases.
There was a little animation posted by somebody and I can't seem to find it again. Anyway, the caption indicated that the simulation represented a gas under quite a bit of pressure and was slowed down like 2 trillion times. It was good to give some sense of scale (assuming it was indeed accurate) and there was definitely a distribution of speeds. But, that may have been an artifact of the animation since, in addition to knocking into each other, the molecules were also bouncing off the borders.
Empirically (there seems to be a lot of empirically sensible stuff on the subject of sound propagation that's just not true)...anyway, empirically, it would seem that a mass of some gas that is all exposed to the same heat source and has achieved at least near thermal equilibrium would have all the molecules moving at about the same speed. After all, when they collide, they don't exchange any energy, just direction so, I'm not sure why, if they are the same temperature, they aren't all at least very close to the same speed.
Now, something like air, that is a mix of gasses, will have heavier and lighter molecules impacting each other and so, I can see why there would be a significant variation in molecular speeds in air.
That was just a number I picked out of the air that's in common use and didn't sound crazy high like, 2 million psi. What's the pressure deep sea divers experience?
A number of misconceptions and little time to deal with them.
The forces between molecules are not inverse square forces. That only applies to charged particles. The forces are a short range attractive force and a very short range repulsive force. This force is often modeled by a leonard-Jones 6-12 potential.
So, it would be fairly safe to generalize that when someone says that the molecules "collide" it's conceptually accurate? Much like thinking of pool balls knocking into each other when in fact they never do touch.
I have a problem with the "restoring force" thing as a way to explain the speed of sound. I can't make it jibe with the speed of sound remaining constant when there's a change in pressure (and, thus the molecules are physically closer or further apart).
I read an article that said that the attractive force is so weak, at the molecular level, that it can be ignored in most cases.
There is a wide distribution of molecular velocities for a given temperature. Take a look at the Maxwell-Boltman distribution.
There was a little animation posted by somebody and I can't seem to find it again. Anyway, the caption indicated that the simulation represented a gas under quite a bit of pressure and was slowed down like 2 trillion times. It was good to give some sense of scale (assuming it was indeed accurate) and there was definitely a distribution of speeds. But, that may have been an artifact of the animation since, in addition to knocking into each other, the molecules were also bouncing off the borders.
Empirically (there seems to be a lot of empirically sensible stuff on the subject of sound propagation that's just not true)...anyway, empirically, it would seem that a mass of some gas that is all exposed to the same heat source and has achieved at least near thermal equilibrium would have all the molecules moving at about the same speed. After all, when they collide, they don't exchange any energy, just direction so, I'm not sure why, if they are the same temperature, they aren't all at least very close to the same speed.
Now, something like air, that is a mix of gasses, will have heavier and lighter molecules impacting each other and so, I can see why there would be a significant variation in molecular speeds in air.
The speed of propagation is only independent of pressure for the range of pressures for which the ideal gas law is valid. I suspect (but haven't checked) that the ideal gas law is no longer valid for air at 3000 psi.
That was just a number I picked out of the air that's in common use and didn't sound crazy high like, 2 million psi. What's the pressure deep sea divers experience?
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