another good detector would be a silicon carbide (SiC, also known as carborundum). with a SiC detector, you will need a local battery to bias the junction to just below it's conduction threshold (actually this method works with silicon and germanium diodes as well, but the threshold voltages are lower). this is the technique used by the Marconi company back in the early 20th century. the bias is supplied through very large (1Meg) resistors, so that the battery doesn't act as a low impedance path for RF across the diode.
SiC has the added advantage of ZERO reverse recovery time, which makes it work better at high frequencies.
EDIT: SiC Vf=2V, Ge Vf=0.3V, Si Vf=0.7V