Clearly I'm missing a trick here.
Say the input is +100V relative to ground. At a 100/10 ratio 10V is at the divide, partially shunted to 3.3v by the zener. The current which charges the cap is restricted by the 100K resistor.
Say the input is -100V relative to ground. Current flows through the bottom diodes through the 100k. There is also a pull on the PIC's pin.
Say the input is +100V relative to ground. At a 100/10 ratio 10V is at the divide, partially shunted to 3.3v by the zener. The current which charges the cap is restricted by the 100K resistor.
Say the input is -100V relative to ground. Current flows through the bottom diodes through the 100k. There is also a pull on the PIC's pin.